Titlebook: Catalytic and Kinetic Waves in Polarography; Stal’ G. Mairanovskii Book 1968 Springer Science+Business Media New York 1968 Sorption.adsorp

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Maria Norbäck,María José Zapata Camposrt of electrochemically active materials to and from the electrode is determined not only by diffusion but also by the chemical reaction taking place at the electrode surface. With kinetic currents the chemical reactions can take place before the electron transfer, can follow the electron transfer,

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Nicholas B. Frisch,Richard A. Berger increase of the concentration of this component at the electrode. This usually results in a significant increase in the rate of the antecedent reaction taking place at the electrode. The phenomenon is very similar to the adsorption of the depolarizer in the absence of antecedent chemical reactions.

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R. Michael Meneghini,Leonard T. Bullerrbed particles) and in the reaction-layer volume. The observed kinetic current is therefore a mixed, surface—volume current. Usually, the condition for appearance of mixed kinetic currents is a relatively low adsorptivity of the electrochemically inactive depolarizer form (at the given potential). R

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