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Titlebook: Catalytic and Kinetic Waves in Polarography; Stal’ G. Mairanovskii Book 1968 Springer Science+Business Media New York 1968 Sorption.adsorp

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发表于 2025-3-21 17:25:32 | 显示全部楼层 |阅读模式
书目名称Catalytic and Kinetic Waves in Polarography
编辑Stal’ G. Mairanovskii
视频video
图书封面Titlebook: Catalytic and Kinetic Waves in Polarography;  Stal’ G. Mairanovskii Book 1968 Springer Science+Business Media New York 1968 Sorption.adsorp
描述As our knowledge of the mechanism of electrode processes increases, it becomes more and more apparent that the kinetic currents first observed by R. Brdicka and by K. Wiesner in the 1940‘s are very widely encountered. Very many electrode pro­ cesses contain a chemical stage. * This is true primarily of elec­ trode processes that involve organic compounds. Therefore, to understand the mechanism of electrode processes and, particular­ ly, to correctly interpret the results of polarographic investiga­ tions, it is important to know the characteristics and relationships controlling the chemical reactions taking place at the electrode surface. Generally, these reactions are substantially different from ordinary chemical reactions taking place in the bulk of the solution, since the reactions at the electrodes are often affected by the electric field of the electrode and the adsorption of the par­ ticipating compounds . The fact that hydrogen ions usuallY take part in the electro­ chemical reduction of organic compounds makes possible the use of electrochemical methods, particularly polarography, for the study of protolytic reactions. These reactions play an important role in organic chem
出版日期Book 1968
关键词Sorption; adsorption; chemical reaction; chemistry; hydrogen; information; organic chemistry; reactions
版次1
doihttps://doi.org/10.1007/978-1-4899-2831-3
isbn_softcover978-1-4899-2833-7
isbn_ebook978-1-4899-2831-3
copyrightSpringer Science+Business Media New York 1968
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发表于 2025-3-21 22:38:56 | 显示全部楼层
发表于 2025-3-22 01:03:18 | 显示全部楼层
Catalytic Hydrogen Evolution at the Dropping Mercury Electrode Caused by Organic Catalysts, waves. Primarily for this reason, several phenomena described in Chapters IV, V, VI, and VIII (such as, for example, the effect of depolarizer adsorption on electrode processes) were first investigated in detail on catalytic hydrogen waves.
发表于 2025-3-22 08:13:29 | 显示全部楼层
Maria Norbäck,María José Zapata Camposmical reactions [563–569]. The structure of the electrical layer and its effect on the kinetics of electrode processes were summarized in several reviews, among which the outstanding reviews of Damaskin [570], Parsons [571], and of Nürnberg and Stackelberg [572] must be mentioned.
发表于 2025-3-22 09:08:47 | 显示全部楼层
The Effect of the Double-Layer Structure on Electrode Processes,mical reactions [563–569]. The structure of the electrical layer and its effect on the kinetics of electrode processes were summarized in several reviews, among which the outstanding reviews of Damaskin [570], Parsons [571], and of Nürnberg and Stackelberg [572] must be mentioned.
发表于 2025-3-22 15:22:16 | 显示全部楼层
ed by R. Brdicka and by K. Wiesner in the 1940‘s are very widely encountered. Very many electrode pro­ cesses contain a chemical stage. * This is true primarily of elec­ trode processes that involve organic compounds. Therefore, to understand the mechanism of electrode processes and, particular­ ly,
发表于 2025-3-22 17:11:11 | 显示全部楼层
Maria Norbäck,María José Zapata Camposat the electrode surface. With kinetic currents the chemical reactions can take place before the electron transfer, can follow the electron transfer, or may take place parallel with the electrochemical stage. Accordingly, the kinetic waves can be classified into waves corresponding to antecedent, successive, or parallel chemical reactions [44].
发表于 2025-3-22 23:50:36 | 显示全部楼层
Andreas Diedrich,Annette Risberge; Γ. is the quantity of adsorbed compound if the surface is completely covered by a monomolecular layer; c is the concentration of the adsorbed compound in the bulk solution (M); and . is the adsorption coefficient (M.).
发表于 2025-3-23 02:20:30 | 显示全部楼层
Sara Brorström,Alexander Styhreter the transfer of two electrons, two halogen ions are released and a multiple bond is formed between the carbon atoms [468–472]). On electrodes having a small hydrogen overvoltage the hydrogen atoms adsorbed on the electrode can take part in the electrode process (see, for example, [473]).
发表于 2025-3-23 07:47:55 | 显示全部楼层
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