Titlebook: Catalytic and Kinetic Waves in Polarography; Stal’ G. Mairanovskii Book 1968 Springer Science+Business Media New York 1968 Sorption.adsorp

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Electrode Processes with Antecedent Protonation Reaction, the very few electrode processes in which hydrogen ions do not take part is the reduction of aliphatic derivatives of vicinal dihalogen compounds: after the transfer of two electrons, two halogen ions are released and a multiple bond is formed between the carbon atoms [468–472]). On electrodes havi

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Catalytic Hydrogen Evolution at the Dropping Mercury Electrode Caused by Organic Catalysts, is one of the most complicated electrochemical processes. However, since, in catalytic processes, the catalyst is completely regenerated at the dropping electrode surface, the development of equations for catalytic currents and the explanation of different effects came much earlier than for kinetic

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The Effect of Composition of Aqueous Organic Solvents on the Polarographic Behavior of Organic Comperistic properties are [841]: 1) significant adsorptivity of organic depolarizers on the electrode surface, leading usually to a significant increase in the rate of the processes taking place on the electrode and at the electrode; 2) participation of hydrogen ions in the potential determining step;

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The Effect of Antecedent Metal Ion Discharge on Polarographic Reduction Waves of Organic Compounds,e nature of the electrode metal and is called the null point of the metal (E.). The E. values for various metals are different. Thus for mercury E. is equal to -0.21 V (versus a normal hydrogen electrode); for copper, -0.04 V; zinc, -0.66 to -0.69 V. The most negative E. values are for Na (-1.7 to -