Titlebook: Application of Transition Metal Catalysts in Organic Synthesis; L. Brandsma,H. D. Verkruijsse,S. F. Vasilevsky Book 1999 Springer-Verlag B

Spinous-Process

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Nickel- and Palladium-Catalyzed Cyanatiori of ,,-Halides and ,,-Triflates,heating of an aryl or hetaryl bromide or iodide with copper(I) cyanide at elevated temperatures, using high-boiling solvents such as DMF. 1-Bromo-l-alkynes (RC=C-Br) react under milder conditions to give alkynenitriles [2]...Apparently the reaction does not proceed to completion with a combination o

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Couplings of Acetylenes with ,,-Halides,lladium (II) chloride and copper (I) iodide. Somewhat earlier, in the same year, two other research groups [2,3] had communicated similar couplings under different conditions, using only palladium catalysts. Such . to ..-couplings were earlier only possible under forced conditions (Stephens-Castro c

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Nickel- and Palladium-Catalyzed Cross-Coupling Reactions with Organometallic Intermediates,kel compounds, such as dichloro [1,2-bis(diphenylphosphino)ethane] nickel(II) (NiCl.-dppe) and nickel acetylacetonate (Ni(acac).). Somewhat later coupling reactions were carried out with other organometallic compounds unDEr the influence of various nickel and palladium catalysts.

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