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Titlebook: Sulfur-Centered Reactive Intermediates in Chemistry and Biology; Chryssostomos Chatgilialoglu,Klaus-Dieter Asmus Book 1990 Plenum Press, N

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Electrochemical Reduction of Some Sulfur Compounds, limited number of examples can be discussed. The reactions chosen are meant to illustrate the diversity of the reductions of sulfur compounds rather than to attempt a full coverage. A survey of the electrochemistry of organic sulfur compounds covering the literature up to 1975 is available;. in thi
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Photocatalytic Formation of Sulfur-Centered Radicals by One-Electron Redox Processes on Semiconductreactive free radical intermediates upon band-gap illumination of semiconducting materials. Depending on the individual material properties it is possible, for example, in an aqueous solvent to form primary radicals such as hydroxyl and sulfhydrol radicals or hydrated electrons. It is the microscopi
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Structure and Reaction Mechanisms in Sulphur-Radical Chemistry Revealed by E.S.R. Spectroscopy,or industrial importance, and they are increasingly implicated in a number of important biological processes. Although their mediation in chemical reactions has long been invoked, direct proof of their involvement — and their full characterization — has largely been the result of the relatively rece
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Beam Experiments as a Means for the Generation of Elusive Sulfur-Containing Molecules,able and lead to isomerization, polymerization or dissociation.. The diluted gas phase which exists in a mass spectrometer is ideally suited for the study of isolated molecules. First of all, as the experiments are conducted in the absence of any counterions and solvents one does not have to account
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Dications from Cyclic Polythioethers, been presented.. These new sulfur species are of particular interest and become attractive if one could prepare the derivatives bearing multithia centers (tri-, tetra, etc.) since their cation radicals or dications once formed could play an important role in the development of a new field in organo
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