Titlebook: Sulfur-Centered Reactive Intermediates in Chemistry and Biology; Chryssostomos Chatgilialoglu,Klaus-Dieter Asmus Book 1990 Plenum Press, N

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,Electronic Transitions in Sulfur-Centered Radicals by Means of MSXα Calculations,/visible absorption and/or ESR spectra. Spectral information are sometimes insufficient for an unequivocal characterization of the transient species. Their identification could be achieved by comparing the optical absorption spectra with the energy and intensity of electronic transitions computed us

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The Electronic Properties of Sulfur-Containing Substituents and Molecules: An ab initio Study,arbon-centered cationic, radical and anionic reaction sites and a directly bonded sulfide, sulfoxide or sulfone substituent. These three substituents have been modelled by the —SH, —(SO) and —(SO.)H groups, respectively. Hartree-Fock (RHF for closed-shell and UHF for radical systems) optimizations f

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Alkanethiylperoxyl Radicals,of these radicals, their formation and reactions is very recent and, to a certain extent, this class of radicals represent the expansion and importance of organosulfur reactive intermediates in various branches of chemistry. In fact, it is believed that these reactive species play important roles in

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Single Electron Transfer in Aliphatic Nucleophilic Substitution, a polar two-electron mechanism in which the nucleophile transfers two electrons to the new bond which is established to the electrophilic center. Depending on the reaction order the abbreviations S.1 and S.2 were used for first-order and second-order reactions, respectively.