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Titlebook: Statistical Physics of Fluids; Basic Concepts and A V. I. Kalikmanov Book 2001 Springer-Verlag Berlin Heidelberg 2001 Density Functional Th

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楼主: 浅吟低唱
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978-3-642-07511-7Springer-Verlag Berlin Heidelberg 2001
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Theories of correlation functions,oute to thermodynamics is used: the energy, pressure, or compressibility equation of state. Thus, in using density expansion techniques, one does not confront the problem of thermodynamic consistency.
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Equations of state,e will not in general be the same if calculated on the basis of another one. For example, the pressure calculated from the virial equation will differ from the pressure found by means of the compressibility equation.
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Monte Carlo methods,ion”, “modeling”, and also “numerical experiment.” To make the terminology more precise, the words “statistical” and “computational” are often added. This refinement is related to the fact that statistics requires a lot of observations, attempts or trials, and one cannot do without modern computers.
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Polar fluids,equate description of long-range and anisotropic interactions comprises the main source of difficulties that arise in theoretical models and simulation studies. A full microscopic theory of a polar fluid is an immensely difficult problem also due to the fact that:
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