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Titlebook: Reverse Micelles; Biological and Techn P. L. Luisi,B. E. Straub Book 1984 Springer Science+Business Media New York 1984 structure

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Micelles and Reversed Micelles: A Historical Overview,icroemulsions. The current model of micelle formation was suggested about fifty years ago, while the quantitative development of thermodynamic and kinetic models is relatively recent. A very important development was the mapping of complete phase equilibria of surfactant/water/amphiphilic or non-pol
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Naturally Occurring Amphiphiles: Aspects of Their Phase Behavior,mbranes and serum lipoproteins. They usually make up 25–50% of the dry weight, the exception being myelin, where the phospholipid content amounts to ∼80%. Phospholipids are also commercially important, their technological applications ranging from emulsifiers to ingredients of foodstuffs, cosmetics,
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The Assembly of Amphiphiles: Molecular and Phenomenological Models,ot possible, due to their transient nature. A theoretical treatment without invoking arbitrary constraints is not feasible at the present. On the other hand the mere assignment of symbols is not sufficient for an understanding of the biological processes in membranes and for guiding the adaptation o
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The Problem of Concentration and Reactivity in Reversed Micelles and Water-In-Oil Microemulsions,em with homogeneous solvent media. For water-soluble reactants, insoluble in the dispersion medium, the aim would be to compare reactivity in the aqueous droplets of the microemulsion with bulk aqueous solution. In the case of first-order reactions the measured rate constants (units −s.) may, in mos
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Acidities and Basicities in Reversed Micellar Systems,nteraction taking place in the micellar “water pool, WP”. The subject also bears on the basic question of whether reversed micellar catalysis is due, at least partially, to a change in the physico-chemical properties of the reactants when they are solubilized in the WP. A nice example of an enhanced
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Aggregation States and Dynamics of Nonionic Polyoxyethylene Surfactants,ing centers like ethylene glycol. and form-amide. promote micelle formation similar to that in water. In contrast, in aliphatic hydrocarbon solvents, such as cyclohexane or decane, reverse (or inverted) micelles may form.. However, polar solvents with a single hydrogen bonding center do not appear t
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Dynamic Behavior of Microemulsions,ty and electrical birefringence measurements. A tentative picture of the inversion process from water-in-oil to oil-in-water structures is presented. When the interfacial layer is relatively rigid,droplets can be concentrated to large volume fractions and inversion is relatively sharp. Where the int
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Microemulsions Stabilized by Oleate/Pentanol,rocesses it is important that the uptake and transport to the appropriate solubilization site is rapid, both for water-soluble and oil-soluble material, while in other applications the opposite is desired. In order to better understand the transport mechanism in microemulsion systems we have studied
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