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Titlebook: Redox Systems Under Nano-Space Control; Toshikazu Hirao Book 2006 Springer-Verlag Berlin Heidelberg 2006 Coordination Chemistry.catalysis.

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978-3-642-06736-5Springer-Verlag Berlin Heidelberg 2006
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Multielectron Redox Catalysts in Metal-Assembled Macromolecular Systemshe life reactions and is important for industrial applications. This review focuses on the multielectron transfer reaction facilitated by redox-assembled systems in macromolecular architectures. Recent advances in constructing anano-redox system based on precise assembly of metal complexes in dendritic macromolecules are shown in particular.
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Programmed Metal Arrays by Means of Designable Biological Macromoleculeseven heterogeneous assembly of metal ions in a programmable manner by chemically modiyfing their building blocks. This bottom-up strategy based on biorelated molecules would generate not only a new structuralmotif formetal clusters in the biomolecules but also a metal-triggered information-transfer system.
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Toshikazu HiraoFirst book on redox systems using the novel principle of nano-space control.Future industrial applications are also included.Includes supplementary material:
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Metal-Containing Star and Hyperbranched Polymersto their short history and less perfect three-dimensional structures, it is expected that they will prove to be more accessible functional materials because of their less cumbersome synthetic procedures. Further developments in metal-containing star and hyperbranched polymers can be anticipated in terms of practical applications.
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Realizing the Ultimate Amplification in Conducting Polymer Sensors: Isolated Nanoscopic Pathwayschemes. For optical (fluorescent) sensors a continous filmwith facile three-dimensional transport is optimal. In resistivity-based sensors the ultimate gain is realized when the carriers are constrained to nanoscopic pathways. In this architecture the carriers are forced to traverse barriers that ar
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