Titlebook: Redox Systems Under Nano-Space Control; Toshikazu Hirao Book 2006 Springer-Verlag Berlin Heidelberg 2006 Coordination Chemistry.catalysis.

存心

Metal-Containing ,-Conjugated Materials with new properties. Phosphines are used as ligands for the attachment of transition metal centers to conjugated backbones, with a variety of coordination modes observed, depending on the available coordination sites at the metal and the position of the phosphine substituent. Several examples are d

吞没

Redox Active Architectures and Carbon-Rich Ruthenium Complexes as Models for Molecular Wiresnium compounds are used for the synthesis of bimetallic complexes as models for conductive molecular wires including diynyl, bis-allenylidene bridges, and original odd-numbered carbon chains via innovative C-C bond coupling reactions. These systems also appear as building blocks to connect two carbo

ECG769

拥挤前

Multielectron Redox Catalysts in Metal-Assembled Macromolecular Systemshe life reactions and is important for industrial applications. This review focuses on the multielectron transfer reaction facilitated by redox-assembled systems in macromolecular architectures. Recent advances in constructing anano-redox system based on precise assembly of metal complexes in dendri

foodstuff

Triruthenium Cluster Oligomers that Show Multistep/Multielectron Redox Behaviorluster units with different redox potentials. To the best of our knowledge, the present compounds show the largest number of well-characterized and well-separated single-electron redox processes reported thus far. As an extension of this sudy, we are now making dendrimers comprised of the present Ru

alleviate

defray

Calculus

ear-canal

现实

Nano Meccanoredox conditions are applied, thus turning them into functional nanoscale machines for a range of different applications. The key to switching lies in the fact that the redox states of the molecular components determine the vast preference of one (co-)conformation over all others. The switching of t