Titlebook: New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation; Rui Shang Book 2017 The Editor(s) (if app

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Transition Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplingshat find versatile applications in the construction of carbon–carbon and carbon–heteroatom bonds. The use of relatively cheap and stable carboxylic acids to replace organometallic reagents enables the decarboxylative cross-coupling reactions to proceed with good selectivities and functional group to

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Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Haction is potentially useful for laboratory-scale synthesis of aryl and alkenyl esters. Pd catalyst with bidentate phosphine ligands was found as the optimal catalyst, and unlike other reported decarboxylative couplings, copper is not needed as support catalyst in this reaction. The theoretical calcu

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Synthesis of Polyfluorobiaryls via Copper-Catalyzed Decarboxylative Couplings of Potassium Polyfluorction can be used for the preparation of polyfluoroaromatic compounds and polyfluorostilbene. The reactants used in the reaction are easily accessible nonvolatile polyfluorobenzoate salts. Mechanistic studies suggest that decarboxylation occurs at first on copper(I) to generate a polyfluorophenylcop

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