| 书目名称 | New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation |
| 编辑 | Rui Shang |
| 视频video | |
| 概述 | Nominated as an outstanding PhD thesis by the University of Science and Technology of China.Highlights a series of highly efficient decarboxylative coupling reactions that will be of interest to synth |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | .This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. .The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner.. |
| 出版日期 | Book 2017 |
| 关键词 | Metal catalysis; C-C bond formation; Decarboxylation; Palladium-catalyzed decarboxylative coupling; Carb |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-981-10-3193-9 |
| isbn_softcover | 978-981-10-9813-0 |
| isbn_ebook | 978-981-10-3193-9Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |
发表于 2025-3-21 18:50:58
