Titlebook: New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation; Rui Shang Book 2017 The Editor(s) (if app

集合

978-981-10-9813-0The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor

欲望小妹

New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation978-981-10-3193-9Series ISSN 2190-5053 Series E-ISSN 2190-5061

FOVEA

狼群

Construction of C(sp3)–C(sp2) Bonds Via Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryly useful for the synthesis of some functionalized pyridines, quinolines, pyrazines, benzoxazoles, and benzothiazoles. Theoretical analysis shows that the nitrogen atom at the 2-position of the heteroaromatics directly coordinates to Pd(II) in the decarboxylation transition state.

为宠爱

Palladium-Catalyzed Decarboxylative Couplings of Nitrophenyl Acetate Salts and Its Derivatives with des and chlorides. Because the nitro group can be easily converted to many other functional groups in synthetic organic chemistry, this reaction provides a new path for the synthesis of diverse functionalized 1,1-diaryl methanes and their derivatives.

PACT

Palladium-Catalyzed Decarboxylative Benzylation of α-Cyano Aliphatic Carboxylate Salts with Benzyl Eibits good functional group compatibility and proceeds under relatively mild conditions. A diverse range of quaternary, tertiary, and secondary β-aryl nitriles can be conveniently prepared by this method with good to excellent yield, and many of them are difficult to be synthesized by strong base-mediated nucleophilic substitution.

不合

Recent Developments of Iron-Catalyzed Directed C–H Activation/C–C Bond Formation ReactionsDriven by the interest in chemical utilization of ubiquitous metals that are abundant and non-toxic, iron catalysis has become a rapidly growing area of research, and iron-catalyzed C–H activation is actively explored in recent years. In this chapter, I summarize the developments of iron-catalyzed C–H activation that emerged recently.

逃避现实

Rui ShangNominated as an outstanding PhD thesis by the University of Science and Technology of China.Highlights a series of highly efficient decarboxylative coupling reactions that will be of interest to synth

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湿润

ethods are explained using practical examples and step-by-step analyses readily accessible for non-mathematicians. All of the novel chapters have been internationally published by the authors in peer-reviewed j978-94-007-9405-4978-94-007-2863-9