Titlebook: Nanoscale Probes of the Solid/Liquid Interface; Andrew A. Gewirth,Hans Siegenthaler Book 1995 Springer Science+Business Media Dordrecht 19

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Exposition

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The Initial Stages of Electrolytic Copper Deposition: An Atomistic View, tunneling microscopy (STM). For the underpotential deposition of Cu on Au(111), the structure-determining role of anions is emphasized. In case of bulk deposition the important role of surface imperfections as nucleation centers for Cu is highlighted with the STM. In addition, the marked influence

健壮

Scanning Probe Microscopy Studies of Copper Electrodeposition,n-situ scanning probe microscopy (SPM). This chapter reviews the major in-situ SPM studies of bulk copper deposition and highlights the valuable submicroscopic information which can be obtained with these techniques. Particular emphasis is placed on describing the growth morphology of the deposit an

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Frisky

Electrochemical and , STM Studies of UPD and OPD of Metals in Different Model Systems,l)/Ag. are reviewed. The results are discussed on an atomic level with respect to the mechanism of metal deposition. It is shown that the 2-D UPD adlayers act as precursors for the subsequent OPD process determining the epitaxy and the nucleation and growth mechanism of the 3-D metal bulk phase. Inv

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,Harmony of Electrochemical Results, , STM Observations and , SXRS Data, at Gold Faces — Aqueous Sol. More recently . probes: Scanning Tunneling Microscopy and Surface X Ray Scattering at ordered gold electrodes in contact with aqueous solutions, have yielded local structural information on an atomic scale which are significantly in harmony with conventional observations. The Scanning Tunneling Mi