| 书目名称 | Metal-Metal Bonds and Clusters in Chemistry and Catalysis |
| 编辑 | John P. Fackler |
| 视频video | |
| 丛书名称 | Industry-University Cooperative Chemistry Program Symposia |
| 图书封面 |  |
| 描述 | This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton‘s discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containi |
| 出版日期 | Book 1990 |
| 关键词 | Chemical reaction; Niob; Osmium; Ruthenium; catalysis; electrochemistry; lithium; metals; molybdenum; organom |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-1-4899-2492-6 |
| isbn_softcover | 978-1-4899-2494-0 |
| isbn_ebook | 978-1-4899-2492-6 |
| copyright | Springer Science+Business Media New York 1990 |
发表于 2025-3-21 18:41:46
