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Titlebook: Metal-Metal Bonds and Clusters in Chemistry and Catalysis; John P. Fackler Book 1990 Springer Science+Business Media New York 1990 Chemica

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Selective Oxidation Chemistry on Soluble Oxides: A Progress Report simulate them with homogeneous analogues. The detailed mechanisms of methanol dehydrogenation and ethylene epoxidation are unclear, and even the vaguest outlines of the C-H activation mechanism involved in xylene and butane oxidations are obscure.
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Reactivity of Dinuclear and Tetranuclear Clusters of Molybdenum and Tungstent. Recent studies of the activation of carbon monoxide by W.(OR). and W.(OR). clusters are presented with the latter providing the first example of the stoichiometric cleavage of C≡O to carbide and oxide ligands on a cluster.
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Theoretical Studies of Dinuclear Compounds with Multiple Metal-Metal Bondsnds containing multiple bonds of order up to four have been synthesized, and a wealth of data concerning their structure, properties, and reactivity has been collected.. An exciting aspect of research in this field is the central role that both qualitative and quantitative electronic structure theor
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Reactivity of Dinuclear and Tetranuclear Clusters of Molybdenum and Tungstenctive elimination sequences. Principles pertaining to the design of a catalytic system are discussed in light of the above and specific attention is given to the hydrogenation and isomerization of alkenes by W.(H).(OPr.).. Recent studies of the reductive coupling and selective cross coupling of keto
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Metal Clusters in the Solid Statecompounds, cluster and metal-metal bonded species occur in binary halides (Nb, Ta, Mo, W, Re),. oxides (Nb, Mo, W, Tc, Re),. chalcogenides (Zr, Nb, Ta, Mo, Re). and pnictides (Zr, Hf, Nb, Ta, Mo, W, Re).. Ternary and quaternary phases containing a broad representation of metal ions A. (or B.), as in
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