Titlebook: Gas Phase Chemical Reaction Systems; Experiments and Mode J. Wolfrum,H.-R. Volpp,J. Warnatz Conference proceedings 1996 Springer-Verlag Ber

Arbitrary

, Dynamics of Cl + H, ⇌ HC1 + H on a New Potential Energy Surface: The Photosynthesis of Hydrogen Chsurface, variational transition state theory and semiclassical tunneling calculations for both reactions and for other isotopomeric cases, and accurate quantum dynamical calculations of rate constants and state-to-state integral and differential cross sections.

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Cross Sections and Rate Constants for Triatomic and Tetraatomic Reactions:,e considered: The two triatom systems, namely F + H. and F + D., were treated twice employing two different potential energy surfaces. The calculations were carried out within the coupled states approximation. Two atom-triatom reactions were considered: the O + O. reaction, for which the calculation

Project

Mode-Specific Chemistry in the H + HCN and H + N2O Reactions → H. + CN and H + N.O(ν.ν.ν.) → N. + OH, NH + NO. For H + HCN, we study the states (000), (004) and (302), and we find that C-H stretch excitation is much more effective than C-N stretch in lowering the reactive threshold energy and thus enhancing the rate constant. For H + N.O we study the states

NOTCH

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The Hydrogen-Iodine Reactions: 100 Years Later → HI + HI and its reverse HI + HI → H. + I.. Bodenstein measured the rates of the forward and reverse reactions, their equilibria, and their temperature dependence. He found second order kinetic expressions and an Arrhenius temperature dependence for the rate constants. He suggested several mechani

Offset

ETCH

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The Influence of Hindered Rotations on Recombination/Dissociation Kineticst of the reaction path being well approximated by the distance between the centers of mass of the reactants. This formula evaluates classically the contribution to the rate constant from transitional degrees of freedom (those that evolve from free rotations in the limit of infinite separation of the

Repetitions

978-3-642-80301-7Springer-Verlag Berlin Heidelberg 1996

ARM