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Titlebook: Gas Phase Chemical Reaction Systems; Experiments and Mode J. Wolfrum,H.-R. Volpp,J. Warnatz Conference proceedings 1996 Springer-Verlag Ber

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Mode-Specific Chemistry in the H + HCN and H + N2O Reactionsm involves HNNO complex formation. At higher energy (3.3 kcal/mol above threshold and higher), N-O stretch excitation is more effective in enhancing the reaction cross section, due to the dominance of a direct mechanism involving a N-N-O-H transition state.
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https://doi.org/10.1007/978-3-531-90453-5ited iodine molecules H. + I. (hi v) → HI + HI and the termolecular reaction of hydrogen molecules with iodine atoms H. + I + I → HI + HI. The direct bimolecular reaction mechanism and the termolecular reaction mechanism were among those suggested by Bodenstein one hundred years ago.
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The Hydrogen-Iodine Reactions: 100 Years Laterited iodine molecules H. + I. (hi v) → HI + HI and the termolecular reaction of hydrogen molecules with iodine atoms H. + I + I → HI + HI. The direct bimolecular reaction mechanism and the termolecular reaction mechanism were among those suggested by Bodenstein one hundred years ago.
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Spectators and Participants in Vibrational State Controlled Bimolecular Reactionstion. In our study of the reactions of vibrationally excited H.O with H and Cl atoms and vibrationally excited HCN with H, O, and Cl atoms, we find that in direct reactions the nonreacting bond of a molecule is a spectator to the reaction. When the nonreacting bond participates in the reaction, the
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