Titlebook: Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization; M. Aresta,J. V. Schloss Book 1990 Kluwer Academi

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https://doi.org/10.1007/978-1-4615-8273-1C-3 proton of ribulose bisphosphate under normal conditions of saturating CO.. The proton abstracted from C-3 of substrate is conserved and is involved in the subsequent hydration and cleavage of the 6-carbon intermediate, 2-carboxy-3-oxo-D-arabinitol bisphosphate to two molecules of 3-phosphoglycerate.

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https://doi.org/10.1007/978-94-009-0663-1ATP; Oxidation; enzymes; metabolism; photosynthesis

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https://doi.org/10.1007/978-1-4613-2801-8 bicarbonate to form carboxyphosphate, which carboxylates the enolate of biotin possibly via bound CO. as an intermediate. In step (2) carboxybiotin decomposes into bound CO. and the biotin enolate which deprotonates S to form a carbanion, facilitated in some cases by a bound metal. The carbanion is then carboxylated by bound CO..

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Mammalian and Plant Carbonic Anhydrases: Structure, Function, Mechanism and Control,confirmed an earlier observation by a group of physiologists and biochemists that the release of carbon dioxide from hemolyzed blood occurs more rapidly than that expected from the buffer catalyzed rate of conversion of bicarbonate to CO..

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Mechanism of Carboxylation by Biotin Enzymes, bicarbonate to form carboxyphosphate, which carboxylates the enolate of biotin possibly via bound CO. as an intermediate. In step (2) carboxybiotin decomposes into bound CO. and the biotin enolate which deprotonates S to form a carbanion, facilitated in some cases by a bound metal. The carbanion is then carboxylated by bound CO..

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