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Titlebook: Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization; M. Aresta,J. V. Schloss Book 1990 Kluwer Academi

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书目名称Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization
编辑M. Aresta,J. V. Schloss
视频video
丛书名称Nato Science Series C:
图书封面Titlebook: Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization;  M. Aresta,J. V. Schloss Book 1990 Kluwer Academi
描述The activation of carbon dioxide by transition metal complexes has been extensively studied. both experimentally and theoretically. 1 Central reactions in this chemistry are the insertion of C02 into M-X bonds. where X = H. C. 0. and N. (eq. 1-4). We are presently investigating the mechanistic aspects of these reaction processes and will herein deSCribe our current level of understanding. Comparisons of the pathway of the carbon-carbon bond fonning process in transition metal chemistry with the well known analogous chemistry involving organolithium reagents will be presented. Furthermore. the role of these reaction types in both homogeneous and heterogenous catalytic processes leading to useful chemicals will be elaborated. _OM> (1) lMt-H + ~ lMlopi _OM> (2) [Mt-R + C0. 2 [M]0. 2CR _OM> (3) [Mt-OR+ ~ [M]0. 2COR _OM> (4) [Mt-NR2 + C0. 2 [M]~CNR2 Insertion of C02 into the Metal-Hydride Bond. The reaction of anionic group 6 (Cr. Mo. W) transition metal hydrides with carbon dioxide to afford metalloformates occurs readlly at ambient temperature and 2 reduced pressures of carbon dioxide. This insertion process is referred to the normal pathway (Scheme 1). There are no documented cases o
出版日期Book 1990
关键词ATP; Oxidation; enzymes; metabolism; photosynthesis
版次1
doihttps://doi.org/10.1007/978-94-009-0663-1
isbn_softcover978-94-010-6783-6
isbn_ebook978-94-009-0663-1Series ISSN 1389-2185
issn_series 1389-2185
copyrightKluwer Academic Publishers 1990
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发表于 2025-3-21 22:21:32 | 显示全部楼层
1389-2185 ient temperature and 2 reduced pressures of carbon dioxide. This insertion process is referred to the normal pathway (Scheme 1). There are no documented cases o978-94-010-6783-6978-94-009-0663-1Series ISSN 1389-2185
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Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization
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https://doi.org/10.1007/978-3-319-02839-2ion of a doubly reduced complex and a strong electrocatalytic current based on the second reduction wave..[(η.-Me.C.)Ir(L)X]., L = bpy or phen, (phen = 1,10 - phenanthroline), X = Cl, H complexes are shown to be active homogeneous catalysts for the light-driven oxidation of CO to CO. under extremely
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Gabriele Riccardi,Anna V. Ciardulloor the dissolution of sacrificial anodes. Specially designed electrochemical reactors have also been developed. The proper application field for electrocarboxylation processes appears to be the production of fine chemicals.
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Advances in Nutritional Researchbinds with the highest affinity to the central complex and favors its formation. The activation is associated with a dramatic increase in affinity for ATP., K and Mg. We have located, using photoaffinity labeling, the site for AG in the 20 kDa COOH-terminal domain of the enzyme. We propose that this
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Vitamin-Responsive Genetic Abnormalities,nd reductive carboxylations in biosynthesis. The reactions of CO. fixation and reduction are mostly different from those used by the green plants. ., an increasing number of organic compounds were found to require carboxylations, prior to further anaerobic degradation. Examples are the utilization o
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