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Titlebook: Endohedral Lithium-containing Fullerenes; Preparation, Derivat Yutaka Matsuo,Hiroshi Okada,Hiroshi Ueno Book 2017 Springer Nature Singapore

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978-981-13-5290-4Springer Nature Singapore Pte Ltd 2017
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https://doi.org/10.1007/978-981-10-5004-6Endohedral metallofullerenes; EMFs; Nanocarbon materials; Dye-sensitized solar cells; Organic synthesis
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Introduction to Endohedral Fullerenes with the C60 Cage,n the endohedral metallo[60]fullerenes and the specific solvent molecules such as pyridine. Satisfactorily, full chemical characterization of an endohedral metallo[60]fullerene was accomplished with lithium-containing [60]fullerene.
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History of Li@C60,C. suggested that Li in the C. cage enhances its second hyperpolarizability. The resistivity of the Li@C. film was measured as 1.5 kΩ cm, about four orders of magnitude smaller than that of C. films (. 50 MΩ cm).
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Chemical Modification of Li+@C60,the product was highly soluble, even in polar solvents. Iridium and platinum complexes of Li.@C. were synthesized, and an electrostatic attractive interaction between inner Li. and outer transition metals was demonstrated. A supramolecular complex of [10]cycloparaphenylene and Li.@C. was also synthe
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New Directions in Li@C60 Research: Physical Measurements,f Li. motion at low temperature (ca. 2.2 and 2.65 THz) were observed in the THz spectra. The Li atom inside the C. cage in carbon nanotubes was observed by transmission electron microscopy with electron energy loss spectroscopy.
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