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Titlebook: Endohedral Lithium-containing Fullerenes; Preparation, Derivat Yutaka Matsuo,Hiroshi Okada,Hiroshi Ueno Book 2017 Springer Nature Singapore

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发表于 2025-3-21 16:49:49 | 显示全部楼层 |阅读模式
书目名称Endohedral Lithium-containing Fullerenes
副标题Preparation, Derivat
编辑Yutaka Matsuo,Hiroshi Okada,Hiroshi Ueno
视频video
概述Focuses on Li-endohedral C60 among various endohedral metallofullerenes.Provides a broad view from synthesis to application and from chemistry to physics.Presents the history of Li@C60 work from early
图书封面Titlebook: Endohedral Lithium-containing Fullerenes; Preparation, Derivat Yutaka Matsuo,Hiroshi Okada,Hiroshi Ueno Book 2017 Springer Nature Singapore
描述.This book describes the emergent endohedral metallofullerene, lithium-containing fullerene Li@C.60., with an overview from its history to recent application research. The book covers synthesis, preparation, purification, structure, physical and chemical properties, derivatization, computational theoretical studies, and device application of Li@C.60.. Readers can learn cutting-edge nanotechnology of this exotic nanocarbon material, which is expected to deliver future solutions in clean energy and bio devices. This work is by a researcher who has long experience in carbon nanomaterials—more than 15 years with his contributing coworkers. The level of the book is appropriate for graduate students, post-docs researchers, and young faculty members who are interested in nanomaterials from the point of view of chemistry and physics..
出版日期Book 2017
关键词Endohedral metallofullerenes; EMFs; Nanocarbon materials; Dye-sensitized solar cells; Organic synthesis
版次1
doihttps://doi.org/10.1007/978-981-10-5004-6
isbn_softcover978-981-13-5290-4
isbn_ebook978-981-10-5004-6
copyrightSpringer Nature Singapore Pte Ltd 2017
The information of publication is updating

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发表于 2025-3-21 22:01:05 | 显示全部楼层
https://doi.org/10.1057/9780230512917li metal-containing [60]fullerenes were produced by colliding ion beams or plasma with C.. In experiment colliding a lithium ion beam with C., a mass peak assignable to Li@C. was detected. Potassium plasma was also used, and a peak assignable to K@C. was detected by mass spectrometry. Campbell and c
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Dieter Borchmeyer,Ami Maayani,Susanne Villthe encapsulation of Li. inside the C. cage. Two Li.@C. salts, namely [Li.@C.]PF. and [Li.@C.]SbCl., were examined by in-depth crystallographic investigation. [Li.@C.]PF. underwent a phase transition at 370 K from a face-centered-cubic crystal system to a simple cubic system with decreasing temperat
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Um Einen Wagner von Aussen Bittend,ion of Li.@C.. The [5,6]- and [6,6]-isomers of [Li.@PCBM]PF.. were successfully prepared, and the structure of [6,6]-[Li.@PCBM]PF.. was elucidated by X-ray crystallography. The Diels–Alder reaction of Li.@C. was first investigated using cyclopentadiene as a diene. This reaction was fast, with an equ
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https://doi.org/10.1007/978-3-476-05405-0d inner lithium ion. The singlet and triplet excited state energies of Li.@C. (1.94 and 1.53 eV, respectively) were characterized from emission spectra. The triplet state lifetime of Li.@C. was determined to be 49 µs by transient absorption measurements. Photoinduced electron transfer reduction of L
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https://doi.org/10.1007/978-3-531-92504-2at when Li. collides at the center of the 6-membered rings of ., the Li. ion passes through the 6-membered rings and becomes trapped in the C. cage. From the early period of endohedral metallofullerenes research, structural optimization of Li@C. was performed and its electronic structures were inves
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https://doi.org/10.1007/978-3-662-29785-8structures. UPS of Li@C. showed characteristic peaks due to electron transfer from the inner Li to the C. cage. Dielectric measurement for [Li.@C.]. at low temperature revealed a phase transition temperature .. at 24 K. Above .., the Li. ion was localized at two equivalent position, suggesting quant
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