Titlebook: Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds; Stacey L. McDonald Book 2016 Springer International Publishing Switzerl

戏法

Basics of Input-Output Analysistive aminating and acylating reagent. Treatment of zinc enolates with .-acylhydroxylamines provides solely 1,3-dicarbonyl compounds under mild conditions. Introduction of a copper catalyst into the system shifts the reactivity entirely, yielding a-amination products exclusively.

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Eco-Efficiency in Industry and Sciencent compounds. Traditionally, C–N bonds have been synthesized using nucleophilic amines, with transition metal-mediated aminations providing a powerful method towards this end. The importance of nitrogen-containing compounds continues to drive the development of new C–N bond-forming transformations,

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Basics of Input-Output Analysisly relevant molecules. Selective α-amination and α-acylation of esters and amides have been developed, employing .-acylhydroxylamines as a dually reactive aminating and acylating reagent. Treatment of zinc enolates with .-acylhydroxylamines provides solely 1,3-dicarbonyl compounds under mild conditi

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EXTOL

https://doi.org/10.1007/978-1-4020-9902-1for the synthesis of these important heteroaryl amines are highly valuable. Direct amination of heteroarenes and arenes has been achieved in a one-pot C–H zincation/copper-catalyzed electrophilic amination procedure. This amination method provides an efficient and rapid approach to access a diverse

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Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds978-3-319-38878-6Series ISSN 2190-5053 Series E-ISSN 2190-5061

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achlorhydria

intuition

978-3-319-81767-5Springer International Publishing Switzerland 2016

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