Titlebook: Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds; Stacey L. McDonald Book 2016 Springer International Publishing Switzerl

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书目名称Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds影响因子(影响力)学科排名




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异端邪说下

制定

,Selective α-Amination and α-Acylation of Esters and Amides via Dual Reactivity of ,-Acylhydroxylamitive aminating and acylating reagent. Treatment of zinc enolates with .-acylhydroxylamines provides solely 1,3-dicarbonyl compounds under mild conditions. Introduction of a copper catalyst into the system shifts the reactivity entirely, yielding a-amination products exclusively.

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不利

https://doi.org/10.1007/978-1-4020-9902-1range of heteroaromatic and aromatic amines including those previously inaccessible using C–H amination methods. The mild reaction conditions and good functional-group compatibility demonstrate its great potential for the synthesis of important and complex amines.

商议

Book 2016Donald and co-workers reveal this approach to be a rapid and powerful method for accessing a variety of functionalized amines. ..The material outlined in this book shows how McDonald achieved C−H zincation using strong, non-nucleophilic zinc bases and subsequent electrophilic amination of the corres

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厚颜无耻

,Copper-Catalyzed Electrophilic Amination of Heteroarenes and Arenes by C–H Zincation,range of heteroaromatic and aromatic amines including those previously inaccessible using C–H amination methods. The mild reaction conditions and good functional-group compatibility demonstrate its great potential for the synthesis of important and complex amines.

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