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Titlebook: Vibronic Interactions in Molecules and Crystals; Isaac B. Bersuker,Victor Z. Polinger Textbook 1989 Springer-Verlag Berlin Heidelberg 1989

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书目名称Vibronic Interactions in Molecules and Crystals
编辑Isaac B. Bersuker,Victor Z. Polinger
视频video
丛书名称Springer Series in Chemical Physics
图书封面Titlebook: Vibronic Interactions in Molecules and Crystals;  Isaac B. Bersuker,Victor Z. Polinger Textbook 1989 Springer-Verlag Berlin Heidelberg 1989
描述Vibronic interaction effects constitute a new field of investigation in the physics and chemistry of molecules and crystals that combines all the phenomena and laws originating from the mixing of different electronic states by nuclear displacements. This field is based on a new concept which goes beyond the separate descriptions of electronic and nuclear motions in the adiabatic approximation. Publications on this topic often appear under the title of the lahn-Thller effect, although the area of application of the new approach is much wider: the term vibronic interaction seems to be more appropriate to the field as a whole. The present understanding of the subject was reached only recently, during the last quarter of a century. As a result of intensive development of the theory and experiment, it was shown that the nonadiabatic mixing of close-in-energy elec­ tronic states under nuclear displacements and the back influence of the modified electronic structure on the nuclear dynamics result in a series of new effects in the properties of molecules and crystals. The applications of the theory of vibronic in­ of spectroscopy [including visible, ultraviolet, in­ teractions cover the fu
出版日期Textbook 1989
关键词chemistry; cluster; crystal; dispersion; electron; molecule; phase transition; spectra
版次1
doihttps://doi.org/10.1007/978-3-642-83479-0
isbn_softcover978-3-642-83481-3
isbn_ebook978-3-642-83479-0Series ISSN 0172-6218 Series E-ISSN 2364-9003
issn_series 0172-6218
copyrightSpringer-Verlag Berlin Heidelberg 1989
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Springer Series in Chemical Physicshttp://image.papertrans.cn/v/image/982814.jpg
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978-3-642-83481-3Springer-Verlag Berlin Heidelberg 1989
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Spectroscopic Manifestations of Vibronic Effects,troscopic properties of the system. Even when the vibronic coupling is weak, the resulting changes in the spectra can be very significant, especially when the vibronic interaction leads to the appearance of additional spectral lines (for instance, in the rotational absorption spectrum of spherical-top molecules).
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Adiabatic Potentials,In this chapter the adiabatic potential surfaces which are formal solutions of the electronic part of the Schrödinger equation are investigated.
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