Titlebook: Understanding Kinetic Resolution by Hydrolases; Maximizing Enantiose Abir B. Majumder,Kalluri V. S. Ranganath Book 2023 The Editor(s) (if a

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2191-5407 oncept accessible and appealing to graduate students, researchers, and young organic chemists seeking to incorporate hydrolases in their stereoselective synthesis endeavors..978-3-031-46352-5978-3-031-46353-2Series ISSN 2191-5407 Series E-ISSN 2191-5415

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Understanding Enzymatic Kinetic Resolution, hand, indicates the destruction of the plane of symmetry of the starting reactant molecule by regioselective functionalization. Both the processes look very close by nature when the reaction goes but actually are widely different. Present chapter addresses the fundamentals of kinetic resolution aid

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Essential Parameters: Determination and Significance,vity exhibited by an enzyme in kinetic resolution is determined after finding out the values of enantiomeric excess of the products or that of the unreacted remaining substrate at a certain conversion value, and then enantioselectivity is calculated. This may also be calculated from the initial rate

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Enantioselectivity: The Decisive Factors,s depends upon how efficiently these conditions are tuned to achieve a targeted result. This chapter talks about these important factors with thermodynamic interpretation wherever needed and strategies to obtain a high . value.

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Dynamic Kinetic Resolution,hosen enantiomeric product. Many transitional metal complexes have been found to reracemize the enantiomeric substrate (relatively untouched by the enzyme) under the milder conditions (of enzymatic kinetic resolution) and thereby avoiding the harsh conditions aided by chemicals. This improves the at

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Book 2023specific focus on the role of hydrolases in this process. Enzymatic kinetic resolution is a valuable technique for obtaining enantiopure compounds, and hydrolases are highlighted as a crucial class of enzymes widely used in industries for chiral synthesis involving kinetic resolution. The book empha

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Book 2023l product or starting material while maintaining the desired yield. Through illustrative examples, the text aims to make the concept accessible and appealing to graduate students, researchers, and young organic chemists seeking to incorporate hydrolases in their stereoselective synthesis endeavors..