书目名称 | The Role of Rydberg States in Spectroscopy and Photochemistry |
副标题 | Low and High Rydberg |
编辑 | C. Sándorfy |
视频video | http://file.papertrans.cn/919/918992/918992.mp4 |
丛书名称 | Understanding Chemical Reactivity |
图书封面 |  |
描述 | .The aim of this volume is to offer a balanced overview of molecular Rydberg spectroscopy as it has developed over recent decades. Recent evolution has split Rydberg spectroscopy into two apparently distinct fields: the one concerns the low (.n.=3-5) Rydberg states, the other the very high (typically .n.>150) Rydberg states. The former is aimed at spectral levels where Rydberg, valence-shell, and intermediate-type states interact, with a variety of photochemical consequences. The latter considers states extremely close to the ionization limit, from whereionization is possible with a very slight amount of additional energy. Recently developed techniques make it possible to produce ions in well-defined electronic, vibrational and rotational states, including states resulting from spin-orbit or Jahn-Teller splitting. It is then possible to study the structure and reactions of such state-selected ions as well as those of the corresponding neutral molecules. These techniques amount to badly needed high resolution photoelectron spectroscopy. . |
出版日期 | Book 1999 |
关键词 | autoionization; molecule; photochemistry; photoelectron spectroscopy; spectra; spectroscopy; structure |
版次 | 1 |
doi | https://doi.org/10.1007/0-306-46938-3 |
isbn_softcover | 978-1-4020-0414-8 |
isbn_ebook | 978-0-306-46938-1 |
copyright | Springer Science+Business Media B.V. 1999 |