| 书目名称 | The Chemistry of Rotational Isomers |
| 编辑 | Michinori Ōki |
| 视频video | |
| 丛书名称 | Reactivity and Structure: Concepts in Organic Chemistry |
| 图书封面 |  |
| 描述 | Rotation about the Carbon-Carbon single bond is generallyregarded to beunrestricted. About 50 years ago, rotationalisomers were found to exhibitoptical activity: substitutedbiphenyl derivatives. However, the author has investigatedother classes of compounds that have stablerotationalisomers at room temperature. These compounds can serve asmodels for studying very weak intermolecular interactions,that aredifficult to observe. Even diastereotopic groupsshow different chemicalreactivity.From the contents: The "Free Rotation Concept" -RotamerPopulations - Barriers to Rotation - Reactivity ofRotational Isomers. |
| 出版日期 | Book 1993 |
| 关键词 | Amine; Organische Chemie; Stereochemie; Stereoisomere; Stereoisomers; chemistry; information; isolation; nuc |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-51024-3 |
| isbn_softcover | 978-3-642-51026-7 |
| isbn_ebook | 978-3-642-51024-3Series ISSN 0341-2377 |
| issn_series | 0341-2377 |
| copyright | Springer-Verlag Berlin Heidelberg 1993 |
发表于 2025-3-21 19:12:32
