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Titlebook: Synthetic Organic Photochemistry; William M. Horspool Book 1984 Plenum Press, New York 1984 Cycloaddition.Rearrangement.carbon.carbon diox

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ts continued for another fifty years or so to rely almost wholly on thermal rather than photochemical methods of activation in organic synthesis-truly a dark age. When my colleagues and I first began in the 1950s to study the synthetic possibilities of photoexcitation in the chemistry of benzene and its deriv978-1-4612-9668-3978-1-4613-2681-6
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Photoaddition and Photocyclization Processes of Aromatic Compounds,rary to the widely held opinion of the time, was photolabile and would undergo both isomerization. and addition. reactions when subjected to ultraviolet irradiation. From this time there has developed an awareness that the photochemical reactions of arenes have enormous potential both for the synthe
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Enone Photochemical Cycloaddition in Organic Synthesis,is variously referred to as enone photoannelation, enone (2+2) cycloaddition, the de Mayo-Eaton reaction, or the de Mayo reaction. The last name is, however, usually reserved for the cycloaddition of enolized diketones to alkenes.
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Photochemical Addition Reactions in the Benzo(b)Thiophene, Benzo(b)Furan, and Indole Series, products. Benzo(b)thiophene* was discovered by Boes. and represents as much as 12%–15% of the sulfur content of the crude naphthalene fraction of some coal tars. It has also been isolated in various oil shales.. Benzo(b)furan, called coumarone in older literature, is also found in coal tar and was
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Azirine Photolysis and Cycloaddition Reactions,tant place among the best known and most reliable organic photochemical transformations. It is becoming increasingly clear that the photocycloaddition reaction is a versatile synthetic tool which can be used for the construction of complex molecules.. In contrast to the wealth of data associated wit
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