Titlebook: Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis; Koji Kubota Book 2017 Springer Nature Singapore Pte Ltd. 20

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Copper(I)-Catalyzed Intermolecular Borylative Exo-cyclization of Alkenyl Halides Containing Unactivimental and theoretical investigations of the reaction mechanism have also been described. This reaction provides a new method for the synthesis of alkylboronates containing strained cycloalkyl structures from simple starting materials.

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Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aldehydes,organoboronate esters with excellent enantioselectivities. Furthermore, the products could be readily converted to the corresponding functionalized chiral alcohol derivatives through stereospecific C–C bond forming reactions involving the stereogenic C–B bond.

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Book 2017nctionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, an

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Computational Insight into the Enantioselective Borylation of Aldehydes Catalyzed by Chiral Bisphosthe presence of a proton source gave a higher reactivity and a better enantioselectivity in the borylation reaction of aldehydes with a copper(I)/(.)-DTBM-SEGPHOS complex catalyst. This study is particularly valuable toward the development and design of novel enantioselective borylation reactions with polarized carbon–heteroatom double bonds.

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