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Titlebook: Surface Studies with Lasers; Proceedings of the I Franz R. Aussenegg,Alfred Leitner,Max E. Lippitsch Conference proceedings 1983 Springer-V

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Normal (Unenhanced) Raman Scattering from Pyridine Adsorbed on the Low-Index Faces of Silver of a lively debate. Several review articles and a book summarize the current state of thinking on the subject [1–3]. The debate focuses upon the relative importance of two classes of enhancement mechanisms, which are termed electromagnetic (classical) and molecular (sometimes referred to as chemica
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Evidence of “SERS Active Sites” of Atomic Scaleis now better accepted than some years ago that a considerable short-range chemical enhancement mechanism exists beside the classical electromagnetic enhancement |5, 6|. A particular short-range model is the so-called “adatom model”, postulating Raman enhancement for adsorbates at sites of atomic sc
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Contributions of Charge Transfer Complexes and Photochemical Effects to SERS at a Silver Electrodeancement as the surface is illuminated by the laser beam during the oxidization-reduction cycle. This enhancement effect is only obtained when alkali halides are used as electrolytes; it suggest a photodecomposition of the silver halides into metallic clusters. The absorbed molecules may play a role
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SER Scattering by Metal Colloids of division of metals. They lie in size between molecules containing clusters of twenty or more metal atoms [1], which exhibit optical absorption due to one-electron excitation between quantized levels, and bulk metal samples which show collective conduction-electron phenomena. The optical response
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Surface Enhanced Optical Processesrsality of the enhancement process. Although the controversy concerning the total sources of the enhancement is still not settled, most agree that solely electromagnetic effects must play a contributing role. Our recent research, therefore, has made an effort to determine the magnitude of the electr
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Distance Dependence of Surface Enhanced Luminescenceye Basic Fuchsin is separated from the surface of silver particles by a thin layer of SiO.. When the spacer layer thickness is increased from d=0, the luminescence intensity increases and reaches a maximum enhancement of 200 at d ≈ 25 Å, relative to dye on an inert substrate. With further increase i
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