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Titlebook: Surface Forces; B. V. Derjaguin,N. V. Churaev,V. M. Muller Book 1987 Springer Science+Business Media New York 1987 Sorption.adsorption.atm

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Book 1987yers adjacent to an interface. The transi­ tion from the concept of short-range effects that reigned earlier to the concept of long-range forces simultaneously signified the transition from a two-dimensional world to a three-dimensional one, incomparably richer in physicochemical phenomena. This tra
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Forces Near Interfaces,tation of surface tension and capillarity both in the older approach of Clairaut (1743) and Laplace (1806) and in the newer approach of Bakker (1928), based on introducing the pressure tensor in the interfacial region.
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Surface Forces in Transport Phenomena,nographs [1–3]. We begin this chapter with a treatment of less well-known phenomena, viz., capillary osmosis and diffusiophoresis, first analyzed by Derjaguin [4]. Then we treat the thermo-osmosis and thermocrystallization flow of liquids.
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lecular layers adjacent to an interface. The transi­ tion from the concept of short-range effects that reigned earlier to the concept of long-range forces simultaneously signified the transition from a two-dimensional world to a three-dimensional one, incomparably richer in physicochemical phenomena
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Disjoining Pressure,are functions of a special structure of interfacial layers. These forces and effects are responsible for the appearance and magnitude of the interfacial tension and potential jump. The study of interfacial molecular forces has a long history, but these forces are not discussed in detail in the present monograph.
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Conclusion,n the theory of dispersion forces is applied to interlayers of very small thickness (less than 15–20 Å), for here the discreteness of molecular structure becomes a significant factor. The problem of calculating the surface charge in the theory of electrostatic forces still awaits a complete solution.
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Forces Near Interfaces,molecules and ions near interfaces. However, this notion remains vague unless micro-forces are averaged over a sufficiently long time for a certain fixed distance from the interface. In this way we obtain a macroscopic description of surface forces. Such a description forms the basis of the interpre
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