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Titlebook: Structure and Dynamics of Weakly Bound Molecular Complexes; Alfons Weber Book 1987 Springer Science+Business Media Dordrecht 1987 Absorpti

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Microwave Spectra and Weak Intramolecular Hydrogen Bonding in 3-Butene-1-Thiol and N-Methylallylaminable than ... The MW spectra of N-methylallylamine, CH.NHCH.CH=CH., and one deuterated species, CH.NDCH.CH=CH., demonstrate the existence of only one stable conformation. This rotamer is also stabilized by a very weak H bond formed between the methylamino group hydrogen atom and the ir electrons of the double bond.
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The Role of Tunneling Models in Analyzing High-Resolution Spectra of Weakly Bound Molecular Complexmotions can be described as “tunneling” motions. The strong and weak points of the method, which uses group theory to derive phenomenological vibration-rotation-tunneling Hamiltonians, will be described together with some successful applications and some possibilities for future work.
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Spectra of Mixed Dimersntially independent of the other half and only in the homodimer a very weak excition interaction is found. The structure of the benzene dimer does not appear to be T-shaped, but is now found to be rather V-shaped.
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Vibration-Rotation Spectroscopy of ArHCI by Far-Infrared Laser and Microwave/Far-Infrared Laser Doubor, though not conclusively, a potential surface with a double minimum. Further work on other vibrational bands of ArHCI using double resonance methods will elucidate the nature of the surface directly.
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Rotational Spectroscopy of Weakly Bound Complexes: Capabilities and Limitations be accepted, and predictions will be made on what can be anticipated from these methods in succeeding years. Finally, the more general question of all experimental sources of rotational and structural information will briefly be considered in rotational, vibrational, and electronic spectroscopy of weakly bound complexes.
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Pulsed-Nozzle, Fourier-Transform Microwave Spectroscopy of Hydrogen-Bonded Dimersred in the light of some simple rules for predicting the angular geometries of hydrogen-bonded dimers. Finally, some recent results for (SO.,HCN) are presented and the observed angular geometry is compared with the predictions of the Buckingham-Fowler electrostatic model for weakly bound dimers.
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