Titlebook: Stereochemical Analysis of Alicyclic Compounds by C-13 NMR Spectroscopy; James K. Whitesell,Mark A. Minton Book 1987 Chapman and Hall Ltd

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Introduction,ower of the technique is far greater than as a replacement for elemental analysis and indeed can be used to solve complicated structural problems more readily than less straightforward methods such as 2-D . H NMR. techniques.

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Bicyclo[3.1.0]hexanes,The terms exo and endo can be readily used for the cis-fused bicyclo[3.1.0]hexanes.

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Bicyclo[3.2.0]heptanes,The terms exo and endo can be readily used for the cis-fused bicyclo[3.2.0]heptanes (no data for trans-fused compounds was found).

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Bicyclo[3.3.0]octanes,Stereochemistry for the cis-fused series in this system is readily specified by exo and endo. While there are two, relatively conformationally mobile rings present, this sytem is especially well behaved in terms of shift additivity. No significant quantity of data was found for trans-fused bicyclo[3.3.0]octanes.