| 书目名称 | Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations | | 编辑 | Krzysztof Matyjaszewski,Kelly A. Davis | | 视频video | | | 概述 | Highest Impact Factor of all journals ranked by ISI within Polymer Science.Short and concise reports on physics and chemistry of polymers, each written by the world renowned experts.Still valid and us | | 丛书名称 | Advances in Polymer Science | | 图书封面 |  | | 描述 | The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions canno | | 出版日期 | Book 2002 | | 关键词 | Copolymer; Macromolecules; Makromoleküle; Polymer Synthesis; Polymere; Polymers; Polymersynthese; polymer | | 版次 | 1 | | doi | https://doi.org/10.1007/3-540-45806-9 | | isbn_softcover | 978-3-642-07752-4 | | isbn_ebook | 978-3-540-45806-7Series ISSN 0065-3195 Series E-ISSN 1436-5030 | | issn_series | 0065-3195 | | copyright | Springer-Verlag Berlin Heidelberg 2002 |
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发表于 2025-3-21 19:58:48
