Titlebook: Spectra and Dynamics of Small Molecules; Alexander von Humbol Robert W. Field Book 2015 Springer International Publishing Switzerland 2015

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FIR

978-3-319-15957-7Springer International Publishing Switzerland 2015

公理

Spectra and Dynamics of Small Molecules978-3-319-15958-4Series ISSN 0075-8450 Series E-ISSN 1616-6361

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medieval

The Effective Hamiltonian for Polyatomic Molecule Vibration,The vibrational Hamiltonian may be expressed in a basis set consisting of products of harmonic oscillators, one oscillator for each of the 3. − 6 normal modes, where . is the number of atoms in the molecule.

Kinetic

Intramolecular Dynamics: Representations, Visualizations, and Mechanisms,This lecture addresses the question: Stuff moves but eigenstates are stationary. How is motion encoded in Quantum Mechanics? We are concerned with the Time Dependent Schrödinger Equation for the special case of . independent of time.

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Robert W. FieldA clear and concise presentation of essential topics in small-molecule spectroscopy.Author‘s long teaching experience and skilful use of analogy greatly aid understanding.Lectures given as part of the

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Aphorism

The Effective Hamiltonian for Diatomic Molecules,onvert an infinite dimension and internuclear distance-dependent Hamiltonian into a finite dimension matrix model in which the R-dependence is encoded in the ., . dependence of the observed energy levels and transition intensities [2].

和谐

Quantum Beats,se duration is sufficiently short so that its uncertainty-broadened energy width “covers” several non-degenerate eigenstates. This produces a coherent superposition of several eigenstates, and, depending on the detection scheme, results in a sinusoidally oscillating and exponentially decaying signal, usually fluorescence.