Titlebook: Small Ring Compounds in Organic Synthesis VI; Armin Meijere Book 2000 Springer-Verlag Berlin Heidelberg 2000 natural product.organic synth

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Cytology

泥瓦匠

Armin de Meijere,Sergei I. Kozhushkov,Lazaros P. Hadjiarapoglou

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0340-1022 o-2-cyclopropylidene acetate and bicyclopropylidene - in Organic Synthesis as well as a striking new approach to cyclopentenones from easily accessible 1-ethynylcyclopropanols, which is rather general and favorably complements other cyclopentenone syntheses.978-3-662-15648-3978-3-540-48255-0Series ISSN 0340-1022 Series E-ISSN 1436-5049

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CONE

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,Bicyclopropylidene — A Unique Tetrasubstituted Alkene and a Versatile C6-Building Block, discussed.The rich chemistry of bicyclopropylidene beginning with its well-known thermal rearrangement and dimerization, its dihalocarbene additions all the way to its recently developed organometallic chemistry, especially its reactions under the catalysis of palladium and other transition metals,

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,Alkyl 2-Chloro-2-cyclopropylideneacetates—Remarkably Versatile Building Blocks for Organic Synthesi, dipolarophiles and general cyclophiles which leads to a wide range of different types of functionally substituted cyclopropane derivatives, spirocyclopropane-annelated hetero- and carbocycles, mono- and oligocondensed cycles, natural and unnatural amino acids and peptidomimetics, and more. Finally

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