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Titlebook: Silicon-Containing Dendritic Polymers; Petar R. Dvornic,Michael J. Owen Book 2009 Springer Science+Business Media B.V. 2009 Copolymer.Cycl

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Liquid Crystalline Silicon-Containing Dendrimers with Terminal Mesogenic Groups,olecular fragments (.) responsible for LC phase (.) formation. The majority of mesogenic groups consist of rigid rod-, board- (or lath-) and disk-shaped molecular moieties, which play a role of specific “building blocks”, a spontaneous ordering of which leads to the formation of different LC phases.
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Hyperbranched Polycarbosilanes and Polycarbosiloxanes via Hydrosilylation Polymerization, controlled condensation of silanols that are suitable for the synthesis of organic-inorganic hybrid materials. Thus, silicon-based chemistry played a prominent role in the evolution of dendrimer chemistry [1–4], and it did not take long until the first examples of silicon-containing hyperbranched p
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Rearranging Hyperbranched Silyl Ether Polymers,-branched polymers, which exhibit fundamentally different properties from their linear counterparts, including impeded crystallization, minimized chain entanglements, unusual viscosity profiles and solubility behavior (see also Chapter 1). Furthermore, in contrast to linear polymers where the number
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Cyclization Issues in Silicon-Containing Hyperbranched Polymers,hat is generally and largely ignored. However, it is now understood that cyclization is prevalent in polymerizations of this type, and that it can often affect to a significant extent both polydispersity and molecular weights of the polymer products. Since research in hyperbranched polymers has incr
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Hyperbranched Silicon-Containing Polymers via Bimolecular Non-linear Polymerization,eaction mechanism. In contrast to the monomolecular polymerizations of AB. monomers, discussed for the two most prominent groups of silicon-containing hyperbranched polymers in Chapters 12 and 13, this polymerization type involves, as its name implies, two reactive monomers A. and B., where A and B
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