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Titlebook: Selectivity in Chemical Reactions; J. C. Whitehead Book 1988 Kluwer Academic Publishers 1988 Atom.chemical reaction.chemical synthesis.com

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楼主: burgeon
发表于 2025-3-28 16:47:37 | 显示全部楼层
Selectivity of Translational Excitation in Reactive Collisions. The Alkaline Plus Alkyl Halide React X group is outlined. A comparison of these reactive processes with photofragmentation and electron attachment studies of the same RX molecule is also presented revealing important similarities. This common behaviour seems to indicate the same overall selectivity as a result of the similar main dynamics associated with the same R-X bond rupture.
发表于 2025-3-28 21:51:04 | 显示全部楼层
The Effect of Electronic Excitation in the Reactions of Oxygen Atoms with Simple Hydride Molecules into the molecular bond under attack. This results in the transient formation of a strongly-bound singlet intermediate, which may undergo very complex dynamical behaviour before dissociating-to products. This behaviour is illustrated by detailed discussions of the oxygen atom reactions with H. and the hydrogen halides.
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Saturation in Laser-Induced Fluorescence: Detection of Nascent Product Rotational Angular Momentum Ant. In this paper we extend a previous rate equation based treatment of LIF alignment analysis to cover most experimental configurations probing cylindrically symmetric anisotropic distributions produced by photodissociation and inelastic or reactive scattering processes.
发表于 2025-3-29 07:51:32 | 显示全部楼层
Selectivity in Elementary Chemical Reactionsthe following: influence of reagent’s electronic, vibrational and rotational states upon reactivity; spin-orbit effects in elementary reactions, and dynamical aspects of stereochemistry, with special emphasis on orientation and alignment effects in chemical reactions..Selectivity with respect to rea
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Rotational and Steric Effects in Three Centre Reactionsber is presented and the employed preparation methods briefly discussed. A simple dynamical model is described relating the most common rotational effects (initial decline, minimum and subsequent rise of cross sections and rates) to properties of the potential energy surface (anisotropy of the reage
发表于 2025-3-29 23:25:51 | 显示全部楼层
Selectivity of Translational Excitation in Reactive Collisions. The Alkaline Plus Alkyl Halide Reactrom crossed molecular beam studies. The selectivity of the translational excitation of the reactants as well as of the chemical nature of the M, R and X group is outlined. A comparison of these reactive processes with photofragmentation and electron attachment studies of the same RX molecule is also
发表于 2025-3-30 01:32:26 | 显示全部楼层
The Effect of Changing Reagent Translation on Reaction Dynamics: F + CF3I → IF + CF3f neutral reactions has received significant attention [1]. A first series of investigations of the effect of reagent translational energy on the internal state distribution of reaction products was carried out by Polanyi and co-workers, applying the method of infrared arrested relaxation chemilumin
发表于 2025-3-30 05:22:23 | 显示全部楼层
Internal Energy Distributions in AlO Given by the Reactions of Aluminium Atoms with Several Oxidant tom beam is generated by laser ablation of the solid at the exit of a pulsed nozzle and seeding in the supersonic expansion of neutral carrier gases. Velocities ranging from 800 to 3400 ms. are thus obtained. Al atoms are probed, together with the product AlO, by laser-induced fluorescence. The effe
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