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Titlebook: Selective Spectroscopy of Single Molecules; Igor S. Osad’ko Book 2003 Springer-Verlag Berlin Heidelberg 2003 Diffusion.Polymers.Single mol

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楼主: cerebellum
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Two-Photon Start-Stop Correlatorently emit only one photon. In accordance with the principles of quantum mechanics, the instant of time at which a photon is emitted or absorbed is not determined. Therefore the atom will jump at random times between the ground and excited electronic states.
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Full Two-Photon Correlator by an excited atom approaches zero on the time scale of the fluorescence lifetime ... Therefore the start-stop correlator approaches zero on this short time scale and it cannot be used to study the slow relaxation existing in molecular systems.
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Adiabatic Interaction number of atoms, and we have not yet discussed how a system consisting of a single atom can be prepared. If we deal with atoms in the vapor phase, the problem of preparing a trap for a single atom can be solved, although it is not easy to realize from a technical standpoint. However, research with
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Density Matrix for an Impurity Centerite such cooling of the solid and guest molecule, we cannot remove the interaction of the molecule with phonons and tunnelons, because creation of phonons and tunnelons during optical excitation is possible even at .. 0. Such a single molecule interacting with low frequency excitations in a solid is
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One- and Two-Photon Counting Methods in the Spectroscopy of a Single Impurity Centeresults from the interaction with phonons and tunnelons. In Part VI, when we study coherent effects like optical free induction decay or photon echo, we shall see that these off-diagonal elements contain information concerning the phase of the electronic excitation. Therefore .. is called the phase r
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Vibronic Spectra of Complex Moleculesspect to the others. The quanta of these intermolecular vibrations are called phonons. Phonon frequencies occupy a frequency interval from 0 to 100 cm.. Phonons are an important characteristic of a solvent.
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Dynamical Theory of Line Broadeningons are modeled. This approach enables one to find an expression for the line width. However, it is unable to explain the appearance of the PSB or the vibronic spectrum. It has been shown in the last few chapters that all peculiarities of the PSB and vibronic spectrum can be successfully explained w
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