| 书目名称 | STM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface |
| 副标题 | Supramolecular Order |
| 编辑 | Florian Buchner |
| 视频video | http://file.papertrans.cn/861/860368/860368.mp4 |
| 概述 | Nominated by the University of Erlangen for a Springer Theses Prize..A fundamental contribution which has led to a new level of understanding in the field of self-assembly of large organic molecules.. |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | The functionalization of surfaces on the nanoscale is one of the most fascinating and at the same time challenging topics in science. It is the key to tailoring catalysts, sensors, or devices for solar energy conversion, whose functional principle is based on the interaction of an active solid surface with another (liquid or gaseous) phase. As an example, planar transition metal complexes adsorbed on solid supports are promising candidates for novel heterogeneous catalysts. An important feature of these catalysts, compared to supported metal clusters, is the fact that the active sites, i. e. , the coordinated metal centers with their vacant axial coordination sites, are well de?ned and uniform. Metalloporphyrinoids are particularly suitable in this respect because they combine a structure forming element—the rigid molecular frame, which often induces long range order—with an active site, the coordinated metal ion. Its planar coordination environment leaves two axial coordination sites available for additional ligands. If adsorbed on a surface, one of these axial sites is occupied by the underlying substrate. The resulting electronic interaction with the surface can be used to tailo |
| 出版日期 | Book 2010 |
| 关键词 | Porphyrinoids; STEM; STM; Scanning Tunneling Microscopy; Scanning Tunneling Spectroscopy; Self-assembly; S |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-14840-8 |
| isbn_softcover | 978-3-642-26595-2 |
| isbn_ebook | 978-3-642-14840-8Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | Springer-Verlag GmbH Berlin Heidelberg 2010 |
|Archiver|手机版|小黑屋|
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