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Titlebook: Ruthenium Catalysts and Fine Chemistry; Christian Bruneau,Pierre H. Dixneuf Book 2004 Springer-Verlag Berlin Heidelberg 2004 Inorganic Che

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书目名称Ruthenium Catalysts and Fine Chemistry
编辑Christian Bruneau,Pierre H. Dixneuf
视频video
概述Each volume of Topics in Organometallic Chemistry provides the broad scientific readership with comprehensive summary and critical overview of a topic in organometallic chemistry.Research in this rapi
丛书名称Topics in Organometallic Chemistry
图书封面Titlebook: Ruthenium Catalysts and Fine Chemistry;  Christian Bruneau,Pierre H. Dixneuf Book 2004 Springer-Verlag Berlin Heidelberg 2004 Inorganic Che
描述.Molecular ruthenium catalysts, during the last decade, have provided new indispensable synthetic methods that cannot be promoted by other catalysts, and they now constitute an emerging field for the selective preparation of fine chemicals. The major reaction types for carbon-carbon and carbon-heteroatom bond formation, most of them with atom economy, are comprehensively discussed by leading experts. The authors highlight the most important discoveries in ruthenium catalysis and propose activation processes, some of them being still controversial. They illustrate the innovation and usefulness in organic synthesis of specific reactions including carbocyclization, cyclopropanation, olefin metathesis, carbonylation, oxidation, transformation of silicon containing substrates, and show novel reactions operating via vinylidene intermediates, radical processes, inert bonds activation as well as catalysis in water. Therefore, the reader will receive a balanced view of this rapidly developing field..
出版日期Book 2004
关键词Inorganic Chemistry; Organic Chemistry; Organometallics; catalysis; chemistry
版次1
doihttps://doi.org/10.1007/b10989
isbn_softcover978-3-642-05815-8
isbn_ebook978-3-540-40027-1Series ISSN 1436-6002 Series E-ISSN 1616-8534
issn_series 1436-6002
copyrightSpringer-Verlag Berlin Heidelberg 2004
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978-3-642-05815-8Springer-Verlag Berlin Heidelberg 2004
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Cyclopropanation with Ruthenium Catalysts, the metal center and to construct appropriate setereochemical environments. Some of the related carbene complexes of ruthenium, thought to be intermediates for the corresponding cyclopropanation reactions, have been isolated and characterized.
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Selective Carbonylations with Ruthenium Catalysts, reactions, but presents the most significant developments of the last 10 years. The emphasis is on novel and synthetic transformations of genuine value to organic chemists. Especially, this review will focus on carbonylative cycloadditions and carbonylation of C–H bonds. The review is generally organized according to the nature of the reaction.
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