| 书目名称 | Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis |
| 编辑 | Su Yong Go |
| 视频video | |
| 概述 | Highlights new chemical phenomena using light or electricity.Introduces in detail the photochemical and electrochemical activation of C(sp3)-based precursors.Shares detailed information on various mec |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | .This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization..The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, althoughthe backbone structure of organic compounds comprises carbon fragments.. |
| 出版日期 | Book 2024 |
| 关键词 | C(sp2)C(sp3); Ni/Ir Dual Catalysis; C(sp3)-Heteroatom; Nickel Dual Catalysis; Photoredox; C(sp3)B Bond |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-981-99-8994-2 |
| isbn_ebook | 978-981-99-8994-2Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |
发表于 2025-3-21 18:44:18
