| 书目名称 | P Phosphorus | | 副标题 | Mononuclear Compound | | 编辑 | Werner Behrendt,Ulrich W. Gerwarth,Joachim Wagner, | | 视频video | | | 丛书名称 | Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition | | 图书封面 |  | | 描述 | This volume C 1 is the first supplement volume to "Phosphor" C which was published in 1965 and covers the compounds of phosphorus. Starting with the binary species formed between phosphorus and hydrogen, the present volume deals with the neutral mononuclear compounds PH through PH ; the ions featuring the same stoichiometric composition are s covered in separate sections. PH and PH are the major initial gaseous decomposition products of PH and, thus, also 2 J intermediates in many of its gas-phase reactions. Both molecules and their ions have been thoroughly investigated by a variety of modern, high-resolution spectroscopic methods during the last three decades. The coverage of their physical, and mostly molecular, properties re presents the largest part of the first two chapters (PH and ions pp. 2 to 47; PH and ions pp. 47 2 to 111). PH is the only compound described in this volume which is thermally stable under normal J conditions. It is the phosphorus analog of ammonia, but exhibits, however, a quite different chemical behavior towards most elements and compounds. The majority of its physical, and in particular spectroscopic, properties have been determined in great detail sin | | 出版日期 | Book 19938th edition | | 关键词 | hydrogen; molecule; reactions | | 版次 | 8 | | doi | https://doi.org/10.1007/978-3-662-08847-0 | | isbn_softcover | 978-3-662-08849-4 | | isbn_ebook | 978-3-662-08847-0 | | copyright | Springer-Verlag Berlin Heidelberg 1993 |
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发表于 2025-3-21 17:17:36
