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Titlebook: Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures; Mahmut Deniz Yilmaz Book 2012 Springer-Verlag Berlin

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书目名称Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures
编辑Mahmut Deniz Yilmaz
视频video
概述Nominated by the University of Twente, Netherlands, for a SpringerTheses Prize.Describes the development and design of new monolayer-based sensing platforms as chemical and biosensors.Provides a wide
丛书名称Springer Theses
图书封面Titlebook: Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures;  Mahmut Deniz Yilmaz Book 2012 Springer-Verlag Berlin
描述Deniz Yilmaz‘ thesis describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications. The term “orthogonal supramolecular interactions” refers to non-covalent interactions that do not influence each other‘s assembly properties. Orthogonal self-assembly thus allows extended control over the self-assembly process and promotes new materials properties. The first part of the thesis employs orthogonal host-guest and lanthanide-ligand coordination interaction motifs to create supramolecular luminescent monolayers. The second part of the thesis describes the fabrication of functional monolayers on silicon and gold substrates for applications in electronics. .The results illustrate the power of weak supramolecular interactions to direct the immobilization of functional systems on surfaces. The combination of host-guest and lanthanide-ligand coordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combi
出版日期Book 2012
关键词Anthrax Biomarker Detection; Chemical Monolayer Architecture; Host-guest Chemistry; Lanthanide Fluoresc
版次1
doihttps://doi.org/10.1007/978-3-642-30257-2
isbn_softcover978-3-662-52220-2
isbn_ebook978-3-642-30257-2Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer-Verlag Berlin Heidelberg 2012
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2190-5053 oordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combi978-3-662-52220-2978-3-642-30257-2Series ISSN 2190-5053 Series E-ISSN 2190-5061
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General Introduction,Molecular recognition and self-assembly represent the basic concept of supramolecular chemistry and involved noncovalent interactions. Noncovalent interactions (e.g. hydrogen bonding, metal–ligand coordination, electrostatic, and host–guest interactions) are usually weaker than covalent bonds and th
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Expression of Sensitized Eu3+ Luminescence at a Multivalent Interface,to provide local and efficient sensitized Eu. emission. Coordination of a carboxylate group of the antenna to the Eu. center and noncovalent anchoring of both components to the receptor surface appeared to be prerequisites for efficient energy transfer. A Job plot at the surface confirmed that coord
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A Supramolecular Sensing Platform in a Microfluidic Chip, sensing of two different analyte types: biologically relevant phosphate anions and aromatic carboxylic acids which are important for anthrax detection. An Eu(III)-EDTA complex was bound to .-cyclodextrin monolayers via orthogonal supramolecular host–guest interactions. The self-assembly of the Eu(I
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