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Titlebook: Organosilicon Heteropolymers and Heterocompounds; S. N. Borisov,M. G. Voronkov,E. Ya. Lukevits Book 1970 Springer Science+Business Media N

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书目名称Organosilicon Heteropolymers and Heterocompounds
编辑S. N. Borisov,M. G. Voronkov,E. Ya. Lukevits
视频video
丛书名称Monographs in Inorganic Chemistry
图书封面Titlebook: Organosilicon Heteropolymers and Heterocompounds;  S. N. Borisov,M. G. Voronkov,E. Ya. Lukevits Book 1970 Springer Science+Business Media N
描述There are numerous criteria for measuring the growth and development of branches of chemistry. This valuable book illustrates a particular aspect of the growth of organosilicon chemistry. The extent of this field has developed so greatly in recent years that it now is desirable to reclassify parts to bring together hitherto frag­ mented and relatively disparate sections. This has been accomplished by the presently available large units which have been deSignated as "organosilicon heterocompounds. " Simplified expressions of such classification are structural units of the general type C - Si - heteroelement and heteroelement-C - Si, in which there are attached to the organosilicon moiety elements such as oxygen, nitrogen, metals, etc. This arrangement per­ mits the correlation of extensive material, which will be invalu­ able to chemists in many areas, both in and out of organosi- con chemistry. Because of the wealth of information, the authors are currently engaged in the preparation of companion volumes arranged on this general principle. The scope is broad, and includes material which will prove highly interesting and useful to those in academic, industrial, and governmental circ
出版日期Book 1970
关键词metals; oxygen; silicon
版次1
doihttps://doi.org/10.1007/978-1-4615-8627-2
isbn_softcover978-1-4615-8629-6
isbn_ebook978-1-4615-8627-2
copyrightSpringer Science+Business Media New York 1970
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spect of the growth of organosilicon chemistry. The extent of this field has developed so greatly in recent years that it now is desirable to reclassify parts to bring together hitherto frag­ mented and relatively disparate sections. This has been accomplished by the presently available large units
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Organosilicon Compounds of Group I Elements,nd investigated its properties. Depending on the reaction conditions and the ratio of the starting reagents it was possible to obtain the lithium silicides Li.Si, Li.Si, and a mixture of them, Li.Si. [71, 564, 884, 942].
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Organosilicon Compounds of Elements of the Manganese Subgroup,s with an acetonitrile solution of silicon tetrachloride in the presence of mercuric chloride [1555]. There is the possibility that compounds of this type are obtained by the reaction of hydrates of manganese salts with dimethyldichlorosilane [1300].
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978-1-4615-8629-6Springer Science+Business Media New York 1970
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Organosilicon Compounds of Group III Elements,The simplest method of synthesizing tris(trialkylsilyl) borates is based on the reaction of trialkylchlorosilanes with boric acid [251]:.Thus, boiling boric acid with trialkylchlorosilanes for 12–15 hr gives tris(trialkylsilyl) borates in about 25% yield.
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Organosilicon Compounds of Group V Elements,The reaction of arsenic trichloride with triphenylchlorosilane in benzene in the presence of the calculated amount of 30% ammonium hydroxide forms crystalline tris(triphenylsilyl) arsenite [631]:.The yield of this compound is substantially affected by even slight variations in the rate of addition of AsCl. and the stirring rate.
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Organosilicon Compounds of Group IV Elements,ermasiloxanes, mainly of cyclic structure, containing 2–7.5% germanium [457, 1478]. The inorganic chain contains only about 40% of the amount of germanium introduced into the reaction. This is due to the higher stability (lower tendency for condensation) of dimethylgermanediol in an acid medium in comparison with dimethylsilanediol.
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