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Titlebook: Organometallics in Organic Synthesis; Aspects of a Modern Armin Meijere,Heindirk Dieck Conference proceedings 1988 Springer-Verlag Berlin

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书目名称Organometallics in Organic Synthesis
副标题Aspects of a Modern
编辑Armin Meijere,Heindirk Dieck
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图书封面Titlebook: Organometallics in Organic Synthesis; Aspects of a Modern  Armin Meijere,Heindirk Dieck Conference proceedings 1988 Springer-Verlag Berlin
描述More and more possible applications of organometallic compounds in organic synthesis have been uncovered and a growing number of scientists are attracted to this area of research. This book presents an state-of-the-art account of the successful application of main- and transition metal mediated syntheses. It will stimulate new ideas and initiate further research in all areas of this fascinating chemistry.
出版日期Conference proceedings 1988
关键词Cycloaddition; Rhenium; chemistry; chromium; cobalt; function; metals; organic synthesis; oxygen; palladium; q
版次1
doihttps://doi.org/10.1007/978-3-642-73196-9
isbn_softcover978-3-540-18592-5
isbn_ebook978-3-642-73196-9
copyrightSpringer-Verlag Berlin Heidelberg 1988
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Organorhenium Oxides,Pd) present well-known examples to demonstrate the importance of organometallic model systems for a better understanding of catalytic mechanisms. This is still true even when safe conclusions for heterogeneous processes cannot be drawn from stoichiometric reactions carried out at soluble (homogeneous) species.
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Olefin Insertion into Organyl Metal Bonds,H.CH.)nEt. This mixture is statistically controlled because triethylaluminium and all intermediates (n =1 to n) during this reaction have similar reactivities towards ethylene.. If the M-R bond at the beginning is much more reactive than the M-C bond of the first insertion product, the reaction would terminate after the first step (Scheme 1).
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Selective Reactions on Arene Chromium Complexes,mplement classic arene chemistry such as aromatic electrophilic substitution (Collman, 1987) (Watts, 1982; Muetterties, 1982; Braun, 1985). Particularly useful in this respect are those arene complexes in which the arene is bound to electron withdrawing fragments.
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Novel Metalla-Heterocycles Formed By [3+2], [2+2], and [2+3] Cycloaddition Reactions of Cyclopentadthe metal atom still show the same type of behavior. After the carbonyl compound C.H.Co(PMe.)C0 had been investigated [2], the isocyanide cobalt complexes C.H.Co(PMe.)CNR were prepared and found not only to be good nucleophiles but also useful starting materials for the synthesis of four- and five-membered metalla-heterocycles.
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https://doi.org/10.1007/978-3-642-73196-9Cycloaddition; Rhenium; chemistry; chromium; cobalt; function; metals; organic synthesis; oxygen; palladium; q
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