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Titlebook: On-Surface Synthesis II; Proceedings of the I Dimas G. de Oteyza,Celia Rogero Conference proceedings 2018 Springer International Publishing

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书目名称On-Surface Synthesis II
副标题Proceedings of the I
编辑Dimas G. de Oteyza,Celia Rogero
视频video
概述All about surface-supported synthesis: reaction mechanisms, generation of functional materials and their characterization.Largely based on spectroscopic and microscopic insight with resolution down to
丛书名称Advances in Atom and Single Molecule Machines
图书封面Titlebook: On-Surface Synthesis II; Proceedings of the I Dimas G. de Oteyza,Celia Rogero Conference proceedings 2018 Springer International Publishing
描述.On-surface synthesis is appearing as an extremely promising strategy to create organic nanoarchitectures with atomic precision. Molecular building blocks holding adequate functional groups are dosed onto surfaces that support or even drive their covalent linkage. The surface confinement and the frequent lack of solvents (most commonly being performed under vacuum conditions) create a completely new scenario fully complementary to conventional chemistry. .In a pedagogical way and based on the most recent developments, this volume presents our current understanding in the field, addressing fundamental reaction mechanisms, synthetic strategies to influence the reactions according to our needs, as well as the ultimate growth and characterization of functional materials..Verging on chemistry, physics and materials science, the book is aimed at students and researchers interested in nanochemistry, surface science, supramolecular materials and molecular devices..Chapters "Mechanistic insights into surface-supported chemical reactions", "Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reviels" and "Bottom-up fabrication of atomically precise graphene nanoribbons" of this b
出版日期Conference proceedings 2018
关键词on-surface synthesis; Design at molecular level; surface-supported reactions; surface-supported chemist
版次1
doihttps://doi.org/10.1007/978-3-319-75810-7
isbn_softcover978-3-030-09331-0
isbn_ebook978-3-319-75810-7Series ISSN 2193-9691 Series E-ISSN 2193-9705
issn_series 2193-9691
copyrightSpringer International Publishing AG, part of Springer Nature 2018
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Addressing Long-Standing Chemical Challenges by AFM with Functionalized Tips, covered here include the experimental discrimination of bond orders in single molecules, the characterization of extremely insoluble compounds such as nanographenes, the analysis of the individual components of complex mixtures, and the on-surface generation and identification of highly reactive molecules and intermediates.
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,Dehydrogenative and Dehalogenative Homocoupling Reactions of C–X Groups on Metal Surfaces,he recent achievements of the on-surface reactions of C–X groups activations and C–C couplings, where different carbon species including alkynyl (sp.), alkenyl (sp.), aryl (sp.) and alkyl (sp.) groups are studied.
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,Aryl–Aryl Covalent Coupling on Rutile TiO2 Surfaces,s for thermally triggered on-surface covalent coupling of aryl halides performed directly on rutile titanium dioxide surfaces. We focus our work on important parameters that need to be considered for understanding and optimization of the polymerization reactions on this model transition metal oxide system.
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Kinetic and Thermodynamic Considerations in On-Surface Synthesis,pathways is becoming a frequent practice within on-surface synthesis, but are often considered at 0 K to reduce computational efforts. The recent advances in describing in particular entropic contributions of on-surface reactions provide important guidelines for how calculations can be refined, and
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