Titlebook: On-Surface Synthesis; Proceedings of the I André Gourdon Conference proceedings 2016 Springer International Publishing AG, part of Springer

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Conference proceedings 2016voted to the covalent coupling of molecular precursors on surfaces that allows the preparation of 0D, 1D and 2D molecules that cannot be synthesized in solution. This book is aimed at students and researchers interested in nanochemistry and molecular devices and it gives the reader a pedagogical up-

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2193-9691 ers the theoretical and experimental techniques used to studWith contributions by leading international experts, this book presents a detailed compilation of a new and very active field. It is the first book devoted to the covalent coupling of molecular precursors on surfaces that allows the prepara

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Transition Metals Trigger On-Surface Ullmann Coupling Reaction: Intermediate, Catalyst and Templatelar, we determine the rate constants and activation energy of Cu- and Pd-catalyzed reaction. In the last part, we demonstrate a strategy of using metal coordination template to steer the reaction toward specific products.

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On-Surface Synthesis of Phthalocyanine Compounds,step-by-step by scanning tunneling microscopy and spectroscopy. The last part of this chapter is dedicated to the study of larger precursors functionalized with tetra-carbonitrile groups that react with copper atoms to form original polymers linked by phthalocyanine cores.

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,On-Surface Synthesis by Azide–Alkyne Cycloaddition Reactions on Metal Surfaces,s and a quantitative description of steric effects dominating the coupling mechanism and the regioselectivity of the reaction products. Future perspectives for the bottom-up development of functional nanostructures involving on-surface azide–alkyne cycloadditions are discussed.

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