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Titlebook: Nuclear Magnetic Resonance of Paramagnetic Macromolecules; Gerd N. Mar (Director) Book 1995 Springer Science+Business Media B.V. 1995 chro

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书目名称Nuclear Magnetic Resonance of Paramagnetic Macromolecules
编辑Gerd N. Mar (Director)
视频video
丛书名称Nato Science Series C:
图书封面Titlebook: Nuclear Magnetic Resonance of Paramagnetic Macromolecules;  Gerd N. Mar (Director) Book 1995 Springer Science+Business Media B.V. 1995 chro
描述Since A. Kowalsky‘s first report of the spectrum of cytochrome.c. in 1965, interest in the detection, assignment andinterpretation of paramagnetic molecules has surged, especially in thelast decade. .Two classes of systems have played a key role in the development ofthe field: heme proteins and iron-sulfur proteins. These two systemsare unique in many respects, one of which is that they containwell-defined chromophores, each of which can be studied in detailoutside the protein matrix. They are the most successfully studiedmacromolecules, and the first eight and last six of the seventeencontributions to this book deal with heme and/or iron-sulfur proteins.The middle three chapters survey the progress on, and significantpromise of, more difficult systems which do not possess a chromophore,but which have nevertheless yielded remarkable insights into theirstructure. .
出版日期Book 1995
关键词chromium; cobalt; iron; lanthanum; macromolecule; metals; protein; proteins; spectroscopy; uranium
版次1
doihttps://doi.org/10.1007/978-94-015-8573-6
isbn_softcover978-90-481-4522-5
isbn_ebook978-94-015-8573-6Series ISSN 1389-2185
issn_series 1389-2185
copyrightSpringer Science+Business Media B.V. 1995
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NMR Studies of Nonheme Iron Proteins,ignment by solvent exchangeability, bond connectivity, or through space correlations. We demonstrate these strategies on two proteins of known structure, iron superoxide dismutase and hemerythrin, and on two proteins of unknown structure, isopenicillin N synthase and uteroferrin, the purple acid pho
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Multinuclear Magnetic Resonance and Mutagenesis Studies of Structure-Function Relationships in [2Feed by NMR). Upon reduction, one of the two ferric ions (Fe.) is changed to a ferrous ion (Fe.), and the other remains ferric. Reduced [2Fe-2S] ferredoxins have a total spin number of one-half and produce an EPR signal. [4Fe-4S] cluster types have three possible oxidation states: 3Fe.-Fe., 2Fe.-2Fe.,
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Isotropic Proton Hyperfine Coupling in High Potential [Fe4S4]3+ Models,n, spin distribution, and spin states. These changes can profoundly influence the appearance of spectra, and understanding these can be a key to piecing together accounts of catalytic or redox cycles. In particular, paramagnetic NMR, along with Mossbauer spectroscopy and ENDOR measurements, can ofte
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e English the child at once represents the freedom from responsibility they crave, the idyll they have lost, the savage they fear and the future they seek to shape. These opposed strains find their way into the literary fairy-tale, the first mode of invented fantasy for children.
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Claudio Luchinat,Mario Picciolited by archaeological and anthropological evidence); and (2) humans are symbolic animals—we encode the world through cognitive parameters of time and space. The combination of these two factors might have given males a slight initial advantage over females in terms of the individualization process. But that would have been only the starting point.
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Zhigang Wang,Lawrence Que Jr. these books cover the entire Moon in photographs taken by the robotic spacecraft that have done much of their work behind the Moon, out of communi- tion with Earth for half of their orbital periods. The photog978-1-4899-8806-5978-0-387-73206-0
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